A new luminescent hybrid material based on silica aerogel and a boron-containing coordination compound with 8-hydroxyquinoline was created, and its physicochemical and spectral-luminescent characteristics were studied. A simple scheme for the synthesis of a hybrid luminescent material was developed. Simultaneously with the synthesis of the aerogel, the formation of a boron-containing phosphor was carried out using an isopropanol solution of boric acid and 8-hydroxyquinoline.
View Article and Find Full Text PDFA simple method of synthesis of high pure tris(8-hydroxyquinoline)aluminum (Alq) from commercial available 5N AlO and 8-hydroxyquinolinol has been developed. One-step exchange chemical reaction has been conducted under controlled 8-hydrixyquinoline vapor at a temperature of 190-240 °C with water removal by phosphorus anhydride. According to analysis of inductively coupled plasma mass-spectrometry, the chemical purity of synthesized Alq was 99.
View Article and Find Full Text PDFMorphological study has confirmed the advantage of using doses of single radiation doses 5 Gy (total dose 25 Gy) and inhalation of a hypoxic gas mixture vs other methods of treatment. The study of radiation pathomorphosis showed significants devitalization of the tumor cells realized clinically with a fall in the number of postoperative recurrences and metastases.
View Article and Find Full Text PDFEfficacy of combined treatment (203 patients) and surgical treatment (200 patients) alone was analyzed. In combined treatment either radiation therapy (RT) in the dose 20 Gy over 5 days (group 1) or hypoxyradiotherapy (HRT) in the same doses but in combination with hypoxia (10% oxygen and 90% nitrogen--hypoxic gas mixture HGM-10--group 2) were used in preoperative period. In group 3 HGM-9 (9% oxygen and 91% nitrogen) was used as radioprotector in preoperative period but in increased by 25% radiation doses: total 25 Gy, 5 Gy for 5 days.
View Article and Find Full Text PDFThe data on surgical treatment of 455 patients operated on for primary and recurrent non-organ retroperitoneal tumors (NRT) are discussed. 64.2% of tumors were resected; postoperative lethality was 8.
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