Publications by authors named "A F Shcherbinin"

Chemical Ionization Mass Spectrometry (CIMS) is a well-established analytical method in atmospheric research, process monitoring, forensics, breathomics, and food science. Despite significant advancements in procedural techniques, several instrument configurations, especially operating at different ionization pressures, are typically needed to analyze the full range of compounds from nonfunctionalized parent compounds to their functionalized reaction products. For polar, functionalized compounds, very sensitive detection schemes are provided by high-pressure adduct-forming chemical ionization techniques, whereas for nonfunctionalized, nonpolar compounds, low-pressure chemical ionization techniques have consistently demonstrated superior performance.

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Rehabilitation of patients with adentia and severe atrophy of the alveolar process of the upper jaw is one of the most difficult tasks of modern dentistry. The article demonstrates the experience of using a combination of traditional dental and zygomatic implants to create a fixed prosthesis support on the upper jaw. The combined installation of standard and zygomatic implants is a predictable rehabilitation technique in the case of severe atrophy of the alveolar process of the upper jaw, which reduces the number of surgical stages and reduces the duration of treatment.

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Article Synopsis
  • The study introduces a fast polarity switching method in chemical ionization mass spectrometry, combining a multischeme chemical ionization inlet (MION) with an Orbitrap mass spectrometer to analyze trace species in complex samples effectively.* -
  • By using reagent ions in both positive (diethylammonium) and negative (nitrate) polarities, the system enhances the detection of various compounds, like pesticides and reactive organic species, significantly compared to traditional methods.* -
  • The MION-Orbitrap demonstrated high mass resolving power (280,000) and rapid polarity switching capability, allowing real-time monitoring and detection of a broader range of species, showing its potential as a versatile analytical tool.*
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Article Synopsis
  • - The study explored the detection of various common pesticides using a specialized chemical ionization technique linked to an advanced mass spectrometer, testing different samples like pesticide mixtures and fruit extracts.
  • - A total of 115 pesticides were identified, achieving a high recovery rate of 92% for commonly analyzed chemicals, outperforming traditional gas chromatography methods that only detected about 45-34% of targets.
  • - Experiments involving pineapple samples successfully revealed the presence of several pesticides below their maximum residue levels, demonstrating the methodology's effectiveness for detecting contaminants in real fruit material.
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Illegal explosives are a threat to aviation, transport sector, critical infrastructure and generally to public safety. Their detection requires extremely sensitive instruments with efficient workflows that allow large throughput of items. In this study, we built a trace explosives detection instrument that requires minimal sample treatment and reaches ultra-low picogram level detection limits for many common explosives.

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