The water-gas shift (WGS) reaction is one of the most significant reactions in hydrogen technology since it can be used directly to produce hydrogen from the reaction of CO and water; it is also a side reaction taking place in the hydrocarbon reforming processes, determining their selectivity towards H production. The development of highly active WGS catalysts, especially at temperatures below ~450 °C, where the reaction is thermodynamically favored but kinetically limited, remains a challenge. From a fundamental point of view, the reaction mechanism is still unclear.
View Article and Find Full Text PDFAims: In right ventricular cardiomyopathy (RVCM), intramural scar may prevent rapid transmural activation, which may facilitate subepicardial ventricular tachycardia (VT) circuits. A critical transmural activation delay determined during sinus rhythm (SR) may identify VT substrates in RVCM.
Methods And Results: Consecutive patients with RVCM who underwent detailed endocardial-epicardial mapping and ablation for scar-related VT were enrolled.
Background: Nonischemic cardiomyopathy patients referred for catheter ablation of ventricular arrhythmias (VAs) typically have either inferolateral (ILS) or anteroseptal (ASS) VA substrate locations, with poorer outcomes for ASS. Sympathetic denervation is an important determinant of arrhythmogenicity. Its relation to nonischemic fibrosis in general and to the different VA substrates is unknown.
View Article and Find Full Text PDFThe presence of atrial cardiomyopathy in β-thalassemia major (β-TM) patients complicates their clinical condition. The diagnosis is challenging even with cardiac magnetic resonance (CMR) imaging. Novel echocardiographic techniques are applied to increase the diagnostic yield.
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