Influence of Quadrupolar Molecular Transitions within Plasmonic Cavities.

Optical nanocavities have revolutionized the manipulation of radiative properties of molecular and semiconductor emitters. Here, we investigate the amplified photoluminescence arising from exciting a dark transition of β-carotene molecules embedded within plasmonic nanocavities. Integrating a molecular monolayer into nanoparticle-on-mirror nanostructures unveils enhancements surpassing 4 orders of magnitude in the initially light-forbidden excitation.

Plexcitonic Quantum Light Emission from Nanoparticle-on-Mirror Cavities.

We investigate the quantum-optical properties of the light emitted by a nanoparticle-on-mirror cavity filled with a single quantum emitter. Inspired by recent experiments, we model a dark-field setup and explore the photon statistics of the scattered light under grazing laser illumination. Exploiting analytical solutions to Maxwell's equations, we quantize the nanophotonic cavity fields and describe the formation of plasmon-exciton polaritons (or plexcitons) in the system.

Super- and Subradiant Lattice Resonances in Bipartite Nanoparticle Arrays.

Lattice resonances, the collective modes supported by periodic arrays of metallic nanoparticles, give rise to very strong and spectrally narrow optical responses. Thanks to these properties, which emerge from the coherent multiple scattering enabled by the periodic ordering of the array, lattice resonances are used in a variety of applications such as nanoscale lasing and biosensing. Here, we investigate the lattice resonances supported by bipartite nanoparticle arrays.

Plasmon-assisted Förster resonance energy transfer at the single-molecule level in the moderate quenching regime.

Metallic nanoparticles were shown to affect Förster energy transfer between fluorophore pairs. However, to date, the net plasmonic effect on FRET is still under dispute, with experiments showing efficiency enhancement and reduction. This controversy is due to the challenges involved in the precise positioning of FRET pairs in the near field of a metallic nanostructure, as well as in the accurate characterization of the plasmonic impact on the FRET mechanism.