Two Approaches to the Laser-Induced Formation of Au/Ag Bimetallic Nanoparticles in Supercritical Carbon Dioxide.

Two approaches are proposed for the synthesis of bimetallic Au/Ag nanoparticles, using the pulsed laser ablation of a target consisting of gold and silver plates in a medium of supercritical carbon dioxide. The differences between the two approaches related to the field of "green chemistry" are in the use of different geometric configurations and different laser sources when carrying out the experiments. In the first configuration, the Ag and Au targets are placed side-by-side vertically on the side wall of a high-pressure reactor and the ablation of the target plates occurs alternately with a stationary "wide" horizontal beam with a laser pulse repetition rate of 50 Hz.

Synthesis of Supported Heterogeneous Catalysts by Laser Ablation of Metallic Palladium in Supercritical Carbon Dioxide Medium.

To obtain a supported heterogeneous catalyst, laser ablation of metallic palladium in supercritical carbon dioxide was performed in the presence of a carrier, microparticles of γ-alumina. The influence of the ablation process conditions-including supercritical fluid density, ablation, mixing time of the mixture, and laser wavelength-on the completeness and efficiency of the deposition of palladium particles on the surface of the carrier was studied. The obtained composites were investigated by scanning and transmission electron microscopy using energy dispersive spectroscopy.

Distributed Bragg reflector fiber laser directly written in a composite fiber manufactured by melting phosphate glass in a silica tube.

We demonstrate a single-frequency distributed Bragg reflector (DBR) fiber laser based on the novel erbium-doped composite fiber fabricated by melting phosphate glass in a silica tube. The fabricated composite fiber was single-mode at the wavelength of 1.55 μm; the measured cutoff wavelength was 1.

Increased solubility of molecular hydrogen in UV-exposed germanosilicate fibers.

Spectral properties of photoinduced fiber Bragg gratings written in germanosilicate fibers and subjected to hydrogen loading at a pressure of 150-170 MPa have been studied. It was observed, for the first time to our knowledge, that hydrogen dissolution in the glass network at such high pressures leads not only to a Bragg wavelength shift but also to a considerable alteration of the grating reflectivity. The relative magnitude of the latter effect is independent of the dissolved hydrogen concentration and is defined mainly by the core glass properties and the UV-irradiation conditions.

Fabrication of fiber Bragg gratings with 267 nm femtosecond radiation.

Strong high-quality fiber Bragg gratings with photoinduced refractive-index modulation of more than 10-(3) were written in a Corning SMF-28 fiber, a P(2)O5-doped-core fiber and a pure-silica-core fluorine-doped-cladding fiber by third-harmonic radiation (267 nm, 150 fs and 1.2-1.8x1011 W/cm(2)) of a femtosecond Ti:sapphire laser using a phase mask.