Materials (Basel)
November 2024
This study aimed to develop a technology for synthesizing non-degrading porous coatings that remain stable under the conditions of outer space. Using the magnetron sputtering method, we obtained vanadium-lead system coatings over a wide range of mutual concentrations from 6 to 44.9 at.
View Article and Find Full Text PDFBiomimetics (Basel)
November 2023
New composite hydrogels (CH) based on bacterial cellulose (BC) and poly-1-vinyl-1,2,4-triazole (PVT) doped with orthophosphoric acid (oPA), presenting interpenetrating polymeric networks (IPN), have been synthesized. The mesoscopic study of the supramolecular structure (SMS) of both native cellulose, produced by the strain , and the CH based on BC and containing PVT/oPA complex were carried out in a wide range of momentum transfer using ultra- and classical small-angle neutron scattering techniques. The two SMS hierarchical levels were revealed from 1.
View Article and Find Full Text PDFThe bauxite ores of Kazakhstan were analyzed using Mössbauer spectroscopy, X-ray diffraction and an X-ray fluorescence analysis. Experimental data on the structural-phase composition of bauxites were obtained, and the features of the iron-bearing minerals within them were revealed. The studied bauxites were high in iron.
View Article and Find Full Text PDFIn this work, new composite films were prepared by incorporating the disintegrated bacterial cellulose (BCd) nanofibers and cerium oxide nanoparticles into chitosan (CS) matrices. The influence of the amount of nanofillers on the structure and properties of the polymer composites and the specific features of the intermolecular interactions in the materials were determined. An increase in film stiffness was observed as a result of reinforcing the CS matrix with BCd nanofibers: the Young's modulus increased from 4.
View Article and Find Full Text PDFA series of novel polysaccharide-based biocomposites was obtained by impregnation of bacterial cellulose produced by (BC) with the solutions of negatively charged polysaccharides-hyaluronan (HA), sodium alginate (ALG), or κ-carrageenan (CAR)-and subsequently with positively charged chitosan (CS). The penetration of the polysaccharide solutions into the BC network and their interaction to form a polyelectrolyte complex changed the architecture of the BC network. The structure, morphology, and properties of the biocomposites depended on the type of impregnated anionic polysaccharides, and those polysaccharides in turn determined the nature of the interaction with CS.
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