Interlayer reconstruction phase transition in van der Waals materials.

Van der Waals materials display rich structural polymorphs with distinct physical properties. An atomistic understanding of the phase-transition dynamics, propagation pathway and associated evolution of physical properties is essential for capturing their potential in practical technologies. However, direct visualization of the rapid phase-transition process is fundamentally challenging due to the inherent trade-offs among atomic resolution, field of view and imaging frame rate.

Numerical investigation of coal pillar damage mechanisms for various width-to-height ratios.

Pillar stability has garnered significant attention owing to the effects of pillars on coal resource recovery rate, coal pillar stability, and coal bump risk. This study examined the roadway stability control principles of conventional and yield coal pillars. The conventional coal pillars were designed as load-bearing structures with a high load-bearing capacity to carry most of the abutment load, while yield coal pillars were designed as buffer structures for transferring rapidly increasing abutment loads to adjacent solid coal ribs by progressive deformation.

Identification of Drought Stress-Responsive Genes in Rice by Random Walk with Multi-Restart Probability on MultiPlex Biological Networks.

Exploring drought stress-responsive genes in rice is essential for breeding drought-resistant varieties. Rice drought resistance is controlled by multiple genes, and mining drought stress-responsive genes solely based on single omics data lacks stability and accuracy. Multi-omics correlation analysis and biological molecular network analysis provide robust solutions.

Nanoliter-Scale Sample Preparation for Single-Cell Proteomic Analysis Using Glass-Oil-Air-Droplet Chip.

Single-cell proteomic analyses are of fundamental importance in order to capture biological heterogeneity within complex cell systems' heterogeneous populations. Mass spectrometry (MS)-based proteomics is a promising alternative for quantitative single-cell proteomics. Various techniques are continually evolving to address the challenges of limited sample material, detection sensitivity, and throughput constraints.

Influence of Heat Treatment Condition on the Microstructure, Microhardness and Corrosion Resistance of Ag-Sn-In-Ni-Te Alloy Wire.

Ag-Sn-In-Ni-Te alloy ingots were produced through a heating-cooling combined mold continuous casting technique; they were then drawn into wires. However, during the drawing process, the alloy wires tended to harden, making further diameter reduction challenging. To overcome this, heat treatment was necessary to soften the previously drawn wires.

Effect of Chemical Composition on the Thermoplastic Formability and Nanoindentation of Ti-Based Bulk Metallic Glasses.

A series of TiZrBeNi ( = 4, 6, 8, 10 at.%) and TiZrBeCu ( = 4, 6, 8 at.%) bulk metallic glasses were investigated to examine the influence of Ni and Cu content on the viscosity, thermoplastic formability, and nanoindentation of Ti-based bulk metallic glasses.

Impaired neuronal macroautophagy in the prelimbic cortex contributes to comorbid anxiety-like behaviors in rats with chronic neuropathic pain.

A large proportion of patients with chronic pain experience co-morbid anxiety. The medial prefrontal cortex (mPFC) is proposed to underlie this comorbidity, but the molecular and neuronal mechanisms are not fully understood. Here, we reported that impaired neuronal macroautophagy in the prelimbic cortical (PrL) subregion of the mPFC paralleled the occurrence of anxiety-like behaviors in rats with chronic spared nerve injury (SNI).

Stabilizing Lattice Oxygen through Mn Doping in NiCoO Spinel Electrocatalysts for Efficient and Durable Acid Oxygen Evolution.

Design the electrocatalysts without noble metal is still a challenge for oxygen evolution reaction (OER) in acid media. Herein, we reported the manganese (Mn) doping method to decrease the concentration of oxygen vacancy (V) and form the Mn-O structure adjacent octahedral sites in spinel NiCoO (NiMnCoO), which highly enhanced the activity and stability of spinel NiCoO with a low overpotential (η) of 280 mV at j=10 mA cm and long-term stability of 80 h in acid media. The isotopic labelling experiment based on differential electrochemical mass spectrometry (DEMS) clearly demonstrated the lattice oxygen in NiMnCoO is more stable due to strong Mn-O bond and shows synergetic adsorbate evolution mechanism (SAEM) for acid OER.

Comparative study of CT and MR guided microwave ablation in the treatment of para-vascular VX2 liver tumor model in rabbits.

Objective： To analyze the efficacy of microwave ablation (MWA) guided by computed tomography (CT) and 1.5T magnetic resonance (MR) in the treatment of VX2 para-vascular liver tumor model in rabbits. Materials and Methods Sixty para-vascular VX2 liver tumor models in rabbits were randomly divided into CT-guided microwave ablation group (CT group, n=35) and MR-guided microwave ablation group (MR group, n=35).

Comparison of Cold-Sprayed Coatings of Copper-Based Composite Deposited on AZ31B Magnesium Alloy and 6061 T6 Aluminum Alloy Substrates.

Copper-coated graphite and copper mixture powders were deposited on AZ31B magnesium alloy and 6061 T6 aluminum alloy substrates under different process parameters by a solid-state cold spray technique. The microstructure of the copper-coated graphite and copper composite coatings was visually examined using photographs taken with an optical microscope and a scanning electron microscope. The surface roughness of the coatings was investigated with a 3D profilometer.

NLRP14 Safeguards Calcium Homeostasis via Regulating the K27 Ubiquitination of Nclx in Oocyte-to-Embryo Transition.

Sperm-induced Ca rise is critical for driving oocyte activation and subsequent embryonic development, but little is known about how lasting Ca oscillations are regulated. Here it is shown that NLRP14, a maternal effect factor, is essential for keeping Ca oscillations and early embryonic development. Few embryos lacking maternal NLRP14 can develop beyond the 2-cell stage.

Sequencing and analysis of the complete mitochondrial genome of Thomas 1911 from China and its phylogenetic analysis.

The complete mitogenome sequence of Thomas 1911 was determined using PCR. A circular double-stranded structure makes up the mitochondrial genome of . The complete length of the mitochondrial genome is 16,419 bp.

Understanding the sulphur-oxygen exchange process of metal sulphides prior to oxygen evolution reaction.

Dynamic reconstruction of metal sulphides during electrocatalytic oxygen evolution reaction (OER) has hampered the acquisition of legible evidence for comprehensively understanding the phase-transition mechanism and electrocatalytic activity origin. Herein, modelling on a series of cobalt-nickel bimetallic sulphides, we for the first time establish an explicit and comprehensive picture of their dynamic phase evaluation pathway at the pre-catalytic stage before OER process. By utilizing the in-situ electrochemical transmission electron microscopy and electron energy loss spectroscopy, the lattice sulphur atoms of (NiCo)S particles are revealed to be partially substituted by oxygen from electrolyte to form a lattice oxygen-sulphur coexisting shell surface before the generation of reconstituted active species.

The built-in electric field across FeN/FeN interface for efficient electrochemical reduction of CO to CO.

Nanostructured metal-nitrides have attracted tremendous interest as a new generation of catalysts for electroreduction of CO, but these structures have limited activity and stability in the reduction condition. Herein, we report a method of fabricating FeN/FeN nanoparticles with FeN/FeN interface exposed on the NP surface for efficient electrochemical CO reduction reaction (CORR). The FeN/FeN interface is populated with Fe-N and Fe-N coordination sites respectively that show the desired catalysis synergy to enhance the reduction of CO to CO.

Directional Transformation of Heterometallic Oxo Clusters: A New Approach to Prepare Wide-Bandgap Cathode Interlayers for Perovskite Solar Cells.

Typical wide-band gap cathode interlayer materials are difficulty in reducing interface recombination without limiting charge transport in perovskite solar cells (PSCs). Here, a lead-doped titanium-oxo cluster protected by S-containing ligands is introduced at the interface of perovskite and SnO . By in situ heating, the cluster is transformed into PbSO -PbTi O heterostructure.

A miniaturized microstrip antenna with tunable double band-notched characteristics for UWB applications.

This paper proposes the step-by-step design procedure for obtaining independent dual band-notch performance, which provides a valuable method for designing tunable dual band-notched UWB antenna. The proposed antenna consists of the semicircle ring-like radiating patch with an elliptical-shaped slot and double split ring resonators on the top surface of the substrate and defected ground structure (DGS) on the bottom surface of the substrate. The operating frequencies ranged from 1.

Interlayer Spacing Regulation of Molybdenum Selenide Promotes Electrocatalytic Hydrogen Evolution in Alkaline Media.

The construction of heterostructures is a versatile tactic to enhance catalytic activity. However, it is still elusive to realize the modulation of the interlayer spacing in this way to further improve the performance. Here, strong interfacial coupling between CoSe and MoSe by constructing CoSe /MoSe heterostructures is achieved.

The preparation of ultrastable Al doped CeO supported Au catalysts: Strong metal-support interaction for superior catalytic activity towards CO oxidation.

The classical strong metal-support interaction (SMSI) plays a key role in improving thermal stability for supported Au catalysts. However, it always decreases the catalytic activity because of the encapsulation of Au species by support. Herein, we demonstrate that Al is a functional additive which could effectively improve both catalytic activity and sintering resistant property for H pretreated Al doped CeO supported Au (AuCeAl) catalyst at high temperature.

Achieving ultrahigh electrochemical performance by surface design and nanoconfined water manipulation.

The effects of nanoconfined water and the charge storage mechanism are crucial to achieving the ultrahigh electrochemical performance of two-dimensional transition metal carbides (MXenes). We propose a facile method to manipulate nanoconfined water through surface chemistry modification. By introducing oxygen and nitrogen surface groups, more active sites were created for TiC MXene, and the interlayer spacing was significantly increased by accommodating three-layer nanoconfined water.

The design and synthesis of spinel one-dimensional multi-shelled nanostructures for Li-ion batteries.

The rational design, synthesis, and massive production of one-dimensional (1D) spinel composite oxides with multi-shelled nanostructures are critical for the realization of highly efficient energy conversion and storage. However, owing to the limitations of the synthetic methods, the 1D multi-shelled nanostructures, especially for multi-element oxides and binary-metal oxides, have been rarely fabricated. Herein, we design a facile and general method to fabricate 1D spinel composite oxides with complex architectures.

Sequencing and analysis of the complete mitochondrial genome of the lesser bandicoot rat () from China and its phylogenetic analysis.

The complete mitogenome sequence of the lesser bandicoot rat ( Gray and Hardwicke, 1833) was determined using long PCR. The genome was 16,327 bp in length and contained 13 protein-coding genes, 2 ribosomal RNA genes, 22 transfer RNA genes, 1 origin of L strand replication and 1 control region. The overall base composition of the heavy strand is A (34.

Sequencing and analysis of the complete mitochondrial genome of from China and its phylogenetic analysis.

The complete mitogenome sequence of was determined using long PCR. The genome was 16,947 bp in length and contained 13 protein-coding genes, 2 ribosomal RNA genes, 22 transfer RNA genes, 1 origin of L strand replication and 1 control region. The overall base composition of the heavy strand is A (33.

Development and Validation of a Prognostic Nomogram Based on Residual Tumor in Patients With Nondisseminated Nasopharyngeal Carcinoma.

Objectives: To investigate the prognostic value of residual tumor based on Magnetic resonance imaging(MRI) and establish an effective prognostic nomogram model referring to clinical,pathological and other related factors for predicting prognosis in nasopharyngeal carcinoma.

Methods: Overall, 538 patients with non-metastatic, histologically-confirmed nasopharyngeal carcinoma were retrospectively examined. Data from 397 patients were used for the construction and validation of a nomogram based on the presence of residual tumor.

Intravoxel Incoherent Motion Magnetic Resonance Imaging for Assessing Parotid Gland Tumors: Correlation and Comparison with Arterial Spin Labeling Imaging.

Objective: To compare and correlate the findings of intravoxel incoherent motion (IVIM) magnetic resonance (MR) imaging and arterial spin labeling (ASL) imaging in characterizing parotid gland tumors.

Materials And Methods: We retrospectively reviewed 56 patients with parotid gland tumors evaluated by MR imaging. The true diffusion coefficient (D), pseudo-diffusion coefficient (D*), and fraction of perfusion (f) values of IVIM imaging and tumor-to-parotid gland signal intensity ratio (SIR) on ASL imaging were calculated.